Alaabooyinkayaga ugu muhiimsan: Amino silicone, silicone block, silicone hydrophilic, dhammaan emulsion silikoon, hagaajinta xajinta qoynta, ka hortagga biyaha (Fluorine free, Carbon 6, Carbon 8), kiimikooyinka dhaqidda demin (ABS, Enzyme, Spandex ilaaliyaha, Manganese saarista)

 

Emulsifiers waxaa loo qaybin karaa laba qaybood oo ku salaysan ilaha laga helo: walxaha dabiiciga ah iyo alaabta synthetic. Marka loo eego sifooyinka nidaamka emulsion ee loo sameeyay labada weji, waxa loo qaybin karaa laba nooc: biyaha saliidda (O/W) nooca iyo biyaha saliidda (W/O).

Tilmaamaha ugu badan ee la isticmaalo si loo cabbiro waxqabadka emulsifying waa qiimaha dheelitirka lipophilic hydrophilic (HLB). Qiimaha HLB hooseeya wuxuu muujinayaa in emulsifier uu leeyahay lifolicity xooggan oo u nugul inuu sameeyo biyaha nidaamka saliidda (W/O); Qiimaha sare ee HLB wuxuu muujinayaa biyo-bax xoog leh waxayna u nugul tahay inay samayso saliid ku jirta biyaha (O/W). Sidaa darteed, qiimaha HLB waxa uu leeyahay wax lagu daro gaar ah, kaas oo loo isticmaali karo in lagu diyaariyo kareemka leh taxanaha qiimaha HLB ee kala duwan.

 

[Nooca Emulsifier]

Unugyada Emulsifier waxay leeyihiin laba qaybood oo maxalli ah, hydrophilic iyo lipophilic. Marka loo eego sifooyinka deegaanka ee hydrophilic, waxaa loo qaybin karaa saddex nooc.

1.Emulsifiers ion taban waa emulsifiers kuwaas oo ionize biyaha si ay u sameeyaan kooxo hydrophilic ion taban oo leh alkyl ama kooxaha aryl, sida karboksylates, sulfates, iyo sulfonates. Noocan emulsifier-ga ah ayaa inta badan la isticmaalaa wuxuuna leeyahay mugga wax soo saarka ugu sarreeya. Alaabooyinka caadiga ah waxaa ka mid ah saabuun (C15-17H31-35CO2Na), sodium stearate (C17H35CO2Na), sodium dodecyl sulfate (C12H25OSO3Na), iyo calcium dodecyl benzene sulfonate (qaabdhismeedka qaabdhismeedka: [geli formula]). Ion emulsifiers-ka taban waxay u baahan yihiin in lagu isticmaalo xaaladaha alkaline ama dhexdhexaadka ah oo laguma isticmaali karo xaaladaha acidic. Marka noocyo kala duwan oo emulsifiers ah loo isticmaalo diyaarinta kareemka, emulsifiers anionic waxaa lagu qasi karaa midba midka kale ama emulsifiers nonionic. Ion taban iyo emulsifiers togan lama wada isticmaali karo hal emulsion, sababtoo ah isku darka iyaga ayaa carqaladeyn kara xasiloonida emulsion-ka.

2. Emulsifiers togan oo ion ah ayaa ku dhex milma biyaha si ay u sameeyaan kooxo hydrophilic ion togan oo leh alkyl ama kooxo aryl ah. Waxaa jira noocyo yar oo ka mid ah emulsifier-ka noocaan ah, dhammaantoodna waa kuwa ka soo jeeda amines, sida N-dodecyldimethylamine, oo loo isticmaali karo falcelinta polymerization.

3.Emulsifiers-ka aan lahayn ionic waa nooc cusub oo emulsifier ah oo lagu garto ionization-ka biyaha. Gobolkeeda hydrophilic wuxuu ka kooban yahay kooxo kala duwan, oo ay ku jiraan ether-ka polyoxyethylene iyo ether-ka polyoxypropylene. Qaybteeda lipophilic (alkyl ama aryl) waxay si toos ah ugu xidhan tahay dammaanadda ethylene oxide ether. Alaabada caadiga ah waa para octylphenol polyoxyethylene ether (qaab dhismeed:). Atomyada oksijiinta ee silsiladda polyeter-ka ee emulsifiers-ka aan-ionic-ka ahayn waxay samayn karaan curaarta hydrogen iyo biyaha, taasoo u oggolaanaysa inay ku milmaan biyaha. Waxaa loo isticmaali karaa labadaba xaaladaha acidic iyo alkaline, waxayna leedahay saameyn emulsification wanaagsan. Waxaa si weyn loogu isticmaalaa soo saarista kiimikooyinka, dunta, sunta cayayaanka, batroolka, iyo cinjirka.

 

Noocyada emulsifiers

 

Qaybta 1: Surfactants aan ahayn ionic

 

1. Wax lagu daro Ether-ku-salaysan aan-ionic ahayn

1. Alkylphenol polyoxyethylene ether

1) Nonylphenol polyoxyethylene ether NP taxane ah, Nongfu No. 100 110 120 130 140 Nonylphenol/epoxyethane tirada guud

2) Octylphenol polyoxyethylene ether emulsifier OP taxane, fosfooctyl 10 (sek octylphenol polyoxyethylene ether)

3) Bis, tributylphenol polyoxyethylene ether (C4H9) - O (EO) nH

4) Alkylphenol polyoxyethylene ether polyoxyethylene propylene ether emulsifier No. 11

5) Phenethyl phenol polyoxypropylene polyoxyethylene ether emulsifier No. 12

 

2. Benzylphenol polyoxyethylene ether

1) 2. Tribenzyl phenol polyoxyethylene ether emulsifier BP, Wulu BP, Cloud point 65-70 ℃

2) Dibenzylphenol polyoxyethylene ether Nongyu 300

3) Benzyl dimethyl phenol polyoxyethylene ether Nongyu 400

4) Dibenzyl isopropylfenyl phenol [sidoo kale loo yaqaan dibenzyl diphenol] polyoxyethylene ether emulsifier BC Cloud point 69-71 ℃

5) Dibenzylbiphenylphenol, polyoxypropylene, polyoxyethylene ether, Ningru 31, barta daruuraha 76-84 ℃, qiyaasta hoose, ku habboonaanta ballaaran

 

3. Phenethyl phenol polyoxyethylene ether

1) Phenethyl phenol polyoxyethylene ether caanaha beeraha No. 600 iyo No. 500 xarunta ayaa emulsification ugu fiican ee fosfooraska organic la tirada ethylene oxide ah 20-27 iyo dhibic daruur ah 83-92. Waxaa jira laba nooc:

Triphenylethylphenol polyoxyethylene ether, oo inta badan lagu heli karo saddex tilmaamood

Triphenylethylphenol/epoxyethane (saamiga tirada guud) dhibic Cloud (1% xal aqueous) EO nambarka dheeriga ah

1:2.2-2.3 70-75 20-21 1:2.6-2.7 80-85 24-25
1:3.2-3.3 95-100 30-31
Bisphenethyl phenol polyoxyethylene ether

2) Phenethyl isopropylfenyl phenol polyoxyethylene ether caanaha beeraha 600-2 dhexdhexaad / EO mass dhibic dhibic daruur (1% xal aqueous) EO lambarka dheeraadka
1:2.1-2.3 70-75 17-18 1:2.6-2.8 85-90 20-24

3) Diphenylethyl phenol polyoxyethylene ether emulsifier BS waxay leedahay sifooyin emulsifying wanaagsan leh 500 oo ah sunta cayayaanka fosfooraska ee isku dhafan. Saamiga cufka dhexe/EO waa 1:1.7 1:2 1:2.3 1:2.6 1:3 1:3.5 1:4 dhibic daruur (1% xal aqueous) 51 70 75 82 89 96 86 (5% CaCl2 xal)

4) Diphenylethyldiphenol polyoxyethylene ether

5) Phenethyl naphthol polyoxyethylene ether

 

4. Aalkolada polyoxyethylene ether dufan leh iyo alaab la mid ah

1) Lauryl aalkolada polyoxyethylene ether, oo hadda laga soo saaray aalkolada saliidda qumbaha [badanaa ka kooban aalkolada C12], oo leh wakiilka galinta JFC ee daruuraha 40-50 ℃ iyo wakiilka galinta EA

2) Isooctyl polyoxyethylene ether Igepal CA

3) Octadecanol ku salaysan polyoxyethylene ether Pingjia taxanaha caanaha beeraha No. 200

4) Etriol polyoxyethylene ether Hirst GenapolX taxane Japanese kimistari Softanol taxane ah.

6) Aalkolada dufanka leh ee polyoxyethylene ether

 

5. Phenethyl phenol polyoxyethylene ether polyoxyethylene propylene ether iyo alaab la mid ah.

1) Phenethyl phenol polyoxyethylene ether EPE nooca caanaha beeraha 1601 Ningru 33 waxaa loo isticmaalaa isku dhafka 1656L/1656H, PEP nooca caanaha beeraha 1602 Ningru 34 waxaa loo isticmaalaa isku darka Ningru 0211/0212

2) Phenethyl phenylpropanol polyoxyethylene ether caanaha beeraha 1601-II Cloud point 79-80 ℃, 1602- Ⅱ ℃

3) Phenethyl phenol polyoxyethylene ether

 

6. Fatty amine polyoxyethylene ether

1) Fatty amine [sidoo kale loo yaqaan alkyl amine] ether polyoxyethylene

2) Fatty amide polyoxyethylene ether

3) Alkylamine oxide

4) Quaternary amin alkoxides iyo alaabooyin la mid ah
Qaybta labaad:

Waxyaalaha lagu daro ester-ka ee aan ahayn ionic

1. Aashitada dufanka leh ee ethylene oxide
1) Oleic acid polyoxyethylene ester
2) Stearic acid polyoxyethylene ester
3) Rosin acid polyoxyethylene ester

2. Castor oil epoxyethane adduct iyo asalkiisa, emulsifiers gudaha ee magaca ajnabiga ah BL, Ningru 110 120 130 140 emulsifiers EL, PC

3. Polyol fatty acid esters iyo epoxyethane kooda waxay soo bandhigaan fuuqbaxa sorbitol fatty acid esters: Taxanaha dhererka 20 40 60 80 85 lipophilicity xoogan
Fuuqbaxa sorbitol fatty acid ester epoxyethane adduct: Taxanaha Tween wuxuu leeyahay milmayn biyo ka sarreeya Span

4. Waxyaalaha aan ioniga ahayn ee ku salaysan glycerol oo ah alaabta aasaasiga ah

1) Dimeric glycerol iyo esters fatty acid

2) Diglyceride polypropylene glycol ether

3) Glycerol polyoxyethylene ether polyoxyethylene propylene ether fatty acid ester
Qaybta saddexaad ee ugu weyn:

Waxyaalaha aan ioniga ahayn ee leh baloogyada hydroxyl la joojiyay
1. Wax lagu daro aan-ionic ahayn oo leh qaab-dhismeed summeedka iyo xidhitaanka kooxda hydroxyl
2. Waxyaalaha aan ioniga ahayn ee leh qaabdhismeed asymmetric ah iyo xidhitaanka kooxda hydroxyl

 

Anionic surfactant

 

1. Sulfonic acid cusbo

 

1. Alkylbenzene sulfonate

1) Sodium Dialkylbenzenesulfonate

2) Sodium alkyl aryl sulfonate

3) Sodium dodecylbenzenesulfoncunay (kalsiyum) DBS Na

 

2. Alkyl naphthalene sulfonate

1) Sodium butyl naphthalene sulfonate Nekal Wakiilka qoynta HB

2) Sodium dibutyl naphthalene sulfonate Nekal BX (budada)

3) Sodium diisopropylnaphthalene sulfonate Morwet RP

4) Monomethyl naphthalene sulfonate sodium Morwet M

 

3. Alkyl sulfonate

1) Sodium petroleum sulfonate R waa koox alkyl ah oo isku dhafan oo miisaankeedu yahay 400-500.

2) Sodium Alkenyl Sulfonate RCH=CHCH2SO3Na

3) Sodium hydroxyalkylsulfonate R-CH-CH2-CH2SO3NaOH

 

4. Alkyl succinate sulfonate

1) Sodium alkyl succinate sulfonate penetrant T, wakiilka qoynta CB-102 (diisooctylsuccinate sulfonate), Aerosol IB (sodium dibutyl succinate sulfonate), Aerosol MA (sodium dihexyl succinate sulfonate), Aerosol Ay (sodium dipentyl succinate)

2) Alkyl polyoxyethylene ether succinate sulfonate

3) Alkylphenol polyoxyethylene ether succinate sulfonate SSOPA (Alkylphenol polyoxyethylene ether formaldehyde condensate sodium succinate sulfonate) Caawinta Beeraha 2000 (monoalkylphenyl polyoxyethylene ether succinate sulfonate% 3 xal)

 

5. Alkyl biphenyl ether sulfonate

 

6. Naphthalene sulfonic acid formaldehyde condensate

1) Faafida F ee benzyl naphthalene sulfonate formaldehyde condensate

2) Sodium naphthalene sulfonate formaldehyde condensate NNO

3) Sodium dibutylenesulfonate formaldehyde condensate dispersant NO

4)Methyl naphthalene sulfonate sodium formaldehyde condensate MF

 

7. N-methyl dufan amide ku salaysan saabuunta sulfonate bovine 209 sabbaynaya ganaca T

8. N-alkylacyl sarcosinate Lissapol LS saabuunta

9.Isoropyl sulfate derivatives

 

2. Sulfate

1. Saliida castor Sulfated ee saliida cas ee Turkiye

2. Sulfate alkohol dufan leh ROSO3Na

1) Sodium Lauryl Sulfate oo la beddelay

2) Sodium cetamol sulfate C16H33SO3Na

3) Sodium secondary alcohol sulfate H2n+1CH (CH3) OSO3Na

4) Khamri dufan leh (C12-14) sodium sulfate

3. Khamriga dufanka leh ee polyoxyethylene ether sulfate Maprofix ES (sodium lauryl alcohol polyoxyethylene ether sulfate)
4. Alkyl phenol polyoxyethylene ether sulfate RO (EO) nSO3Na caadi ahaan loo isticmaalo kooxaha alkyl waa nonyl iyo octyl.

5. Caraf udgoon alkylphenol polyoxyethylene ether sulfate

3. Phosphate iyo hypophosphite

1. Alkylphenol polyoxyethylene ether phosphate OO RO (EO) np - (OH) 2 [RO (EO) n] 2-P - (OH) 2 monoester diester
Hadda waxa jira laba taxane: R=C8H17 OPEPO4 iyo R=C9H19 NPEPO4
Magaca Alaabta: Phenolic Ether Phosphate Surfactant MAPP (Monoester), NPEPO4Na (ama K)

2.Phenethylphenol polyoxyethylene ether phosphate ester (nooca acid free) code SPEnPO4 O [- CHCH3] KO (EO) np - (OH) 2 [[- CHCH3] KO (EO) n] 2-P - (OH) 2 monoester diester

3. Fatty acid polyoxyethylene ester phosphate
4. Alkyl phosphate, aryl phosphate O
5. Alkylamine polyoxyethylene ether phosphate ester R=C12-14 n=10-16 monoester, sidoo kale loo yaqaan surfactant MAPRO (EO) np - (OH) 2
6. Khamriga dufanka leh ee polyoxyethylene ether phosphate ester
4. Carboxylate (karboxylate dufan) sida rosin acid saabuun polymer daro

1. Non-ionic nooca
1. Alkylphenol polyoxyethylene ether formaldehyde condensate Nongfu 700

2. 1) Phenylalkylphenol polyoxyethylene ether formaldehyde condensate Ningru No. 36, Nongli No. 700-1 Nongli SPF 2) isopropylphenol polyoxyethylene ether formaldehyde condensate Nongli No. 700-2, Ningru No.37 3) Benzylphenol polyoxyethylene ether formaldehyde condensate Japan Sorpol PPB150, 200

1) Phenethyl phenol polyoxyethylene ether formaldehyde condensate Ningru 36 iyo Nongfu 700-1 Nongfu SPF

2) isopropyl phenyl phenol polyoxyethylene ether formaldehyde condensate Nongjiu 700-2 iyo Ningru 37

3) Benzylphenol polyoxyethylene ether formaldehyde condensate Japan Sorpol PPB150,200

3. Biphenylphenol polyoxyethylene ether formaldehyde condensate

4. Khamriga Polyvinyl oo leh biyo-dhismeed dhammaystiran waa 98-99%, heerka hydrolysis ee leh qayb qayb ahaan waa 88-89%

5. Polyoxyethylene iyo polyoxypropylene block copolymers, oo leh miisaannada molecular polyether ee 2000-3000, waxay leeyihiin awood nadiifin oo wanaagsan, miisaanka unugyaduna waxay leeyihiin kala firdhisanaan wanaagsan, sida epoxyethane epoxybutane copolymer iyo epoxyethane epoxypropane epoxybutane copolymer

2. Nooca Anionic
1. Polycarboxylate polyacrylic acid, sodium polyacrylate, polyacrylamide

2. Alkylphenol polyoxyethylene ether formaldehyde kondensate sulfate SOPA-II (270) SOPA-V (570)

3. Alkyl naphthalene sulfonate formaldehyde condensate iyo noocyo la mid ah MF MSF
4. Phenol formaldehyde condensate sulfonate iyo noocyo la mid ah
5. Methylcellulose iyo asalkiisa
6. Xanthan xanjo XG
7. Lignosulfonate Sodium Lignosulfonate M-9, 16 Deglycosylated Sodium Lignosulfonate M-10 Lignosulfonate Sodium M-14 Condensed Modified Sodium Lignosulfonate M-13, 15 Deglycosylated Sodium Lignosulfonate M-17

Surfactant cationic

1. Nooca cusbada ammonium

1. Alkyl ammonium nooca cusbada

2. Nooca laga soo saaro aashitada dufanka leh ee aalkolada

3. Nooc ka soo saara aashitada dufanka leh ee polyamine
4. Nooca Imidazoline

2. Quaternary ammonium nooca cusbada

1. Alkyl trimethylammonium cusbada nooca dodecyl trimethylammonium chloride 1231 Hexadecyltrimethylammonium chloride 1631 Octadecyltrimethylammonium chloride 1831
2. Nooca cusbada Dialkyldimethylammonium
3. Alkyl dimethyl benzyl ammonium milix nooca dodecyl dimethyl benzyl ammonium chloride 1227 acrylic dheeh wakiilka TAN
4. Nooca milixda ee Pyridine
5. Qaabka cusbada Alkyl isoquinoline
6. Benzyl chloride amine nooca

Surfactant Amphoteric

1. Amino acid nooca

1. Nooca Alanine

2. Nooca Glycine II, nooca betaine III, imidazoline nooca IV, iyo amine oxide waxay la mid yihiin surfactants amphoteric, oo ku habboon labadaba surfactants anionic iyo cationic iyo nonionic surfactants. Waxay soo bandhigaan sifooyinka aan-ionic ee xalalka dhexdhexaadka ah iyo alkalineka iyo sifooyinka cationic daciifka ah ee xalalka acidic.

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