Dulmar: Is barbar dhig caabbinta alkali, dhaqidda saafiga ah, saarista saliidda iyo wax-ka-saarista wax-qabadka alaabooyinka kala duwan ee sida caadiga ah laga heli karo suuqa maanta, oo ay ku jiraan labada qaybood ee inta badan la isticmaalo ee nonionic iyo anionic.
Liiska iska caabinta alkali ee surfactants kala duwan
Iska caabinta alkali ee surfactants waxay ka kooban tahay laba dhinac. Dhanka kale, waa xasilloonida qaab dhismeedka kiimikada, taas oo inta badan lagu muujiyo burburinta hiddo-wadaha hydrophilic by alkali xooggan; Dhanka kale, waa xasilloonida xaaladda isugeynta ee dareeraha aqueous, taas oo inta badan lagu muujiyo saameynta milixda ee baabi'isa dareeraha surfactant oo ka dhigaya surfactant sabeyn ama quusin oo ka sooca biyaha.
Habka tijaabada: Qaado 10g/L oo ah surfactant, ku dar alkali flake, dhig heerkulka la cayimay 120 daqiiqo ka dibna u fiirso, qadarka alkali marka delamination ama saliid bleaching dhacdo waa iska caabbinta ugu badan ee alkali.
Jadwalka soo socdaa wuxuu muujinayaa iska caabbinta alkali ee surfactants caadiga ah ee hadda la heli karo.
| Magaca surfactant | 40℃ | 70℃ | 100 ℃ |
| AEO-5 | Sodium hydroxide 15 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 3g/L |
| AEO-7 | Sodium hydroxide22 g/L | Sodium hydroxide 14 g/L | Sodium hydroxide 5g/L |
| AEO-9 | Sodium hydroxide 30 g/L | Sodium hydroxide24 g/L | Sodium hydroxide 12g/L |
| TX-10 | Sodium hydroxide 19 g/L | Sodium hydroxide 15 g/L | Sodium hydroxide 6g/L |
| OP-10 | Sodium hydroxide27 g/L | Sodium hydroxide22 g/L | Sodium hydroxide 11 g/L |
| Wakiilka wax qabad ee JFC | Sodium hydroxide21 g/L | Sodium hydroxide 16 g/L | Sodium hydroxide 9g/L |
| Dhakhso T ayaa u gala | Sodium hydroxide 10 g/L | Sodium hydroxide7 g/L | Sodium hydroxide 3g/L |
| saabuunta saafiga ah 209 | Sodium hydroxide 18 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 5g/L |
| EL-80 | Sodium hydroxide29 g/L | Sodium hydroxide22 g/L | Sodium hydroxide 8 g/L |
| Laba 80 | Sodium hydroxide22 g/L | Sodium hydroxide 11 g/L | Sodium hydroxide7 g/L |
| Baaxadda 80 | Sodium hydroxide 14 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 5 g/L |
| Sodium dodecylbenzene sulfonate LAS | Sodium hydroxide24 g/L | Sodium hydroxide 16 g/L | Sodium hydroxide 9g/L |
| Sodium dodecyl sulfate SDS | Sodium hydroxide81 g/L | Sodium hydroxide44 g/L | Sodium hydroxide 15g/L |
| Sodium secondary alkyl sulfonate SAS | Sodium hydroxide 30 g/L | Sodium hydroxide22 g/L | Sodium hydroxide 12g/L |
| Sodium decyl-sulfonate AOS | Sodium hydroxide29 g/L | Sodium hydroxide20 g/L | Sodium hydroxide 13 g/L |
| Acid dufan qumbaha diethanolamide | Sodium hydroxide 18 g/L | Sodium hydroxide 8 g/L | Sodium hydroxide3 g/L |
| Khamriga dufanka leh ether sulfate AES | Sodium hydroxide98 g/L | Sodium hydroxide77 g/L | Sodium hydroxide 35g/L |
| Aalkolada dufanka leh ether karboxilate AEC | Sodium hydroxide 111 g/L | Sodium hydroxide79 g/L | Sodium hydroxide 40g/L |
| Clotrimazole (dareere) | Sodium hydroxide 145 g/L | Sodium hydroxide95 g/L | Sodium hydroxide 60g/L |
| Phosphate ee khamriga dufanka leh | Sodium hydroxide 180 g/L | Sodium hydroxide 135 g/L | Sodium hydroxide 110g/L |
| Fosfate esters ee ether-ka khamriga dufanka leh | Sodium hydroxide210 g/L | Sodium hydroxide 147 g/L | Sodium hydroxide 170g/L |
Liiska waxqabadka saafiga ah ee saafiga ah
Isticmaalka hal shay oo ceeriin ah, si waafaqsan heerka qaranka GB13174-2003 ee nadiifinta saabuunta dharka, tijaabi saabuunta saafiga ah ee alaabta ceeriin ee kala duwan sida soo socota: u diyaari alaabta ceeriin leh 250ppm biyo adag si aad u hesho 15% xal fiirsashada alaabta ceeriin , ku dhaq sida waafaqsan GB/T 13174-2003 "Habka tijaabada dhaqidda nadiifinta", cabbir caddaanka dharka kala duwan ee dharka ka hor iyo ka dib, oo xisaabi qiimaha saabuunta R sida waafaqsan qaacidada soo socota:
R(%)=F2-F1
Meesha F1 ay tahay cadaanka ka hor maydhitaanka ee marada wasakhaysan (%), F2 waa qiimaha cadaanka ka dib maydhka ee marada wasakhaysan (%).
Marka uu bato qiimaha R, waa ay sii xoogaysanaysaa awoodda dhaqidda saafiga ah. Heerkan tijaabada ah waxaa loo isticmaali karaa in lagu garto ka saarista wasakhda guud by surfactants oo aan lagu dabaqi karin si ay u muujiso awoodda saarista dufanka iyo dhuka.
| Magaca surfactant | R (%) qiimo |
| AEO-3 | R (%)=3.69 |
| AEO-5 | R (%) = 3.31 |
| AEO-7 | R (%) = 9.50 |
| AEO-9 | R (%) = 12.19 |
| TX-10 | R (%) = 15.77 |
| NP-8.6 | R (%)=14.98 |
| OP-10 | R (%) = 14.55 |
| XL-90 | R (%) = 13.91 |
| XP-90 | R (%) = 4.30 |
| TO-90 | R (%) = 15.58 |
| Tusmada ugu hooseysa ee JFC | R (%) = 2.01 |
| Dhakhso T ayaa u gala | R (%)=0.77 |
| saabuunta saafiga ah 209 | R (%) = 4.98 |
| Sodium dodecylbenzene sulfonate LAS | R (%)=9.12 |
| Sodium dodecyl sulfate SDS | R (%) = 5.30 |
| Sodium decyl-sulfonate AOS | R (%) = 8.63 |
| Sodium secondary alkyl sulfonate SAS | R (%) = 15.81 |
| Khamriga dufanka leh ether sulfate AES | R (%) = 5.91 |
| Aalkolada dufanka leh ether karboxilate AEC | R (%) = 6.20 |
| Clotrimazole (dareere) | R (%) = 15.55 |
| Phosphate ee khamriga dufanka leh | R (%) = 2.08 |
| Fosfate esters ee ethers alkohol baruur leh AEP | R (%)=5.88 |
Isbarbardhigga waxqabadka saarista saliidda ee surfactants kala duwan
Tijaabada saarista saliidda ee surfactant (qaabka heerka saarista saliidda) waxaa loo sameeyaa si waafaqsan GB 9985-2000 Lifaaqa B, iyadoo la isticmaalayo saabuunta caadiga ah sida caanaha caadiga ah. Xisaabi heerka saarista saliidda (C) si waafaqsan qaacidooyinka soo socda:
C = tayada saarista saliidda ee muunadda/tayada saarista saliidda qaabaynta caadiga ah
Qiimaha C ee weyn, ayaa sii xoogeysanaya awoodda saarista saliidda ee surfactant
| Magaca surfactant | De-saliid qiimaha C |
| AEO-3 | De-saliid qiimaha C=1.53 |
| AEO-5 | De-saliid qiimaha C=1.40 |
| AEO-7 | De-saliid qiimaha C=1.22 |
| AEO-9 | De-saliid qiimaha C=1.01 |
| TX-10 | De-saliid qiimaha C=1.17 |
| NP-8.6 | De-saliid qiimaha C=1.25 |
| OP-10 | De-saliid qiimaha C=1.37 |
| XL-90 | Saliid-saarista qiimaha C = 1.10 |
| XP-90 | De-saliid qiimaha C=0.66 |
| TO-90 | De-saliid qiimaha C=1.40 |
| Gudub JFC | De-saliid qiimaha C=0.77 |
| Fatty acid methyl ester ethoxylate FMEE | De-saliid qiimaha C=1.94 |
| Dhakhso T ayaa u gala | De-saliid qiimaha C=0.35 |
| saabuunta saafiga ah 209 | De-saliid qiimaha C=0.76 |
| Sodium dodecylbenzene sulfonate LAS | De-saliid qiimaha C=0.92 |
| Sodium dodecyl sulfate SDS | De-saliid qiimaha C=0.81 |
| Sodium decyl-sulfonate - AOS | De-saliid qiimaha C=0.73 |
| Sodium secondary alkyl sulfonate SAS | De-saliid qiimaha C=0.98 |
| Khamriga dufanka leh ether sulfate AES | De-saliid qiimaha C=0.63 |
| Aalkolada dufanka leh ether karboxilate AEC | De-saliid qiimaha C=0.72 |
| Clotrimazole (dareere) | De-saliid qiimaha C=1.11 |
| Phosphate ee khamriga dufanka leh | De-saliid qiimaha C=0.32 |
| Fosfate esters ee ethers alkohol baruur leh AEP | Saliid-saarka C qiimaha = 0.46 |
Shaxda isbarbardhigga waxqabadka wax-ka-saarista dusha sare
1. Diyaarinta dharka caadiga ah ee dharka
Ku milaan baloogga caadiga ah ilaa 90 darajo oo biyo kulul ah, si fiican u walaaq ka dibna dhex geli marada cad ee caadiga ah, ka saar laba daqiiqo ka dib oo hawo qallaji.
2. Habka tijaabada
Maro dhuxeedka ayaa la gooyaa 5 * 5cm, waxaa lagu dhex milmaa dareeraha shaqada oo leh 5% xoogga alaabta ceeriin, waxaa lagu dhaqaa scillation 10 daqiiqo iyadoo la raacayo heerkulka heerkulka 100 digrii, waxaana lagu maydhay biyo qabow oo buuxa, iyo caddaanka la dhaqay. Maro wax laga cabbiro, oo way sii weynaataa qiimaha caddaanka W waa, way sii fiicnaanaysaa awoodda wax-ka-saarista ee dusha sare.
| Magaca surfactant | W qiimaha |
| AEO-3 | W=67.42 |
| AEO-5 | W=61.98 |
| AEO-7 | W=53.25 |
| AEO-9 | W=47.30 |
| TX-10 | W=46.11 |
| NP-8.6 | W=60.03 |
| OP-10 | W=58.92 |
| XL-90 | W=48.54 |
| XP-90 | W=33.16 |
| TO-7 | W=68.96 |
| TO-9 | W=59.81 |
| Fatty acid methyl ester ethoxylate FMEE | W=77.43 |
| Triethanolamine | W=49.79 |
| Triethanolamine saabuun oleic ah | W=56.31 |
| saabuunta saafiga ah 6501 | W=32.78 |
| Gudub JFC | W=31.91 |
| Dhakhso T ayaa u gala | W=18.90 |
| saabuunta saafiga ah 209 | W=22.55 |
| Sodium dodecylbenzene sulfonate LAS | W=34.17 |
| Sodium dodecyl sulfate SDS | W=27.31 |
| Sodium decyl-sulfonate --AOS | W=29.25 |
| Sodium secondary alkyl sulfonate SAS | W=30.87 |
| Khamriga dufanka leh ether sulfate AES | W=26.37 |
| Aalkolada dufanka leh ether karboxilate AEC | W=33.88 |
| Clotrimazole (dareere) | W=49.35 |
| Phosphate ee khamriga dufanka leh | W=20.47 |
| Fosfate esters ee ethers alkohol baruur leh AEP | W=29.38 |
Waqtiga boostada: Mar-03-2022